From University of Bath 02/10/23

New desalination method could be used to provide drinking water on a small scale in disaster hit areas. Credit: witthaya

Scientists have developed a new method that converts seawater into drinking water that could be useful in disaster zones where there is limited electrical power.

The most popular method for removing salt (sodium chloride) from sea water is reverse osmosis, which uses a porous membrane that allows water molecules through but not salt.

However, this method requires a high pressure and substantial amounts of electricity.

The membrane often clogs up, reducing the efficiency of the process.

The new technique, developed by a team of scientists from the Universities of Bath, Swansea and Edinburgh, doesn’t use any external pressure but instead uses a small amount of electrical energy to pull chloride ions through the membrane towards a positively charged electrode.

Credit: Getty

This causes water molecules to be pushed through at the same time as the chloride, a bit like a piston.

Meanwhile, sodium ions remain on the other side of the membrane, attracted to the negatively charged electrode.

The chloride ions are then recycled back into the chamber containing the salt water and the process is repeated, gradually drawing more and more water molecules through.

Professor Frank Marken, from the University of Bath’s Water Innovation Research Centre and Institute for Sustainability led the study, and predicts this could be used on a small scale where drinking water is needed but there is not the infrastructure available, such as in remote areas or disaster zones.

Molecules, ions and process involved in purification. Technical: (A) Molecular structure of PIM-EA-TB. (B) Molecular structure of methylated PIM-EA-TB. (C) 4-Electrode ionic diode experimental configuration. (D) Schematic of switching of anionic diodes between closed and open states.Credit: ACS Applied Materials & Interfaces

He said: “Currently reverse osmosis uses so much electricity, it requires a dedicated power plant to desalinate water, meaning it is difficult to achieve on a smaller scale.

“Our method could provide an alternative solution on a smaller scale, and because water can be extracted without any side products, this will save energy and won’t involve an industrial scale processing plant.

Photos of purification device. Technical: Photograph of (A) a U-cell with flange and membrane and (B) a 3D-printed (transparent resin) device cell for two coupled arrays of anionic diodes. Credit: ACS Applied Materials & Interfaces

“It could also potentially be miniaturised to use in medical applications such as dosing systems for drugs like insulin.”

So far, the technology is at the proof-of-concept stage, converting only a few millilitres, however the team is now looking for partners for potential collaboration and investment to scale up the process to a litre which will enable them to calculate energy consumption more accurately.

The team would also like to explore other potential applications such as drying processes or recovering water from different sources.

Professor Jan Hoffman, Co-Director of the Water Innovation Research Centre (WIRC) at Bath said: “Zhongkai Li and Frank Marken have developed polymeric materials that can act as a new type of molecular electrical pump for water.

Scanning electron microscopy (SEM, backscatter) images of the backside of a Teflon film with 10 μm microhole coated with a methylated PIM-EA-TB (with 0.1 M iodomethane) membrane. EDX elemental mapping for F, C, O, N, and Cl (shadowing due to the detector position). Credit: ACS Applied Materials & Interfaces Credit: ACS Applied Materials & Interfaces

“I think the discovery can potentially have a revolutionary impact on desalination of seawater and also processes for drying materials and recovering water.

“Of course, there is still a long way to go to create full scale technology based on the recent discovery, but it definitely looks promising and very innovative compared to existing pumping and desalination technologies.”

Dr Mariolino Carta from Swansea University commented: “Microporous materials have enormous potential especially in separation and water purification, but also in catalysis.

“In the future even better materials and processes will be available.”

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