Green hydrogen: ‘Artificial leaf’ becomes better under pressure

Researchers at Helmholtz-Zentrum Berlin in Germany have improved the efficiency of photoelectrochemical cells by increasing operating pressure, potentially enhancing hydrogen production.

From Helmholtz-Zentrum Berlin 05/08/24

Photoelectrochemical (PEC) cell. Credit Feng Liang /HZB

Hydrogen can be produced via the electrolytic splitting of water.

One option here is the use of photoelectrodes that convert sunlight into voltage for electrolysis in so-called photoelectrochemical cells (PEC cells).

A research team at HZB has now shown that the efficiency of PEC cells can be significantly increased under pressure.

Some call it an “artificial leaf.”

Instead of the natural Photosystem II complex that green leaves in nature use to split water with sunlight, photoelectrochemical cells, or PEC cells for short, use artificial, inorganic photoelectrodes to generate the voltage required for the electrolytic splitting of water from sunlight.

Minimising losses

The best-performing devices already achieve impressive energy conversion efficiencies of up to 19 percent.

At such high efficiencies, losses due to bubble formation start to play an important role.

This is because bubbles scatter light, preventing optimal illumination of the electrode.

Moreover, bubbles may block the electrolyte from contacting the electrode surface and thus cause electrochemical deactivation.

To minimize these losses, it would help to reduce the bubble sizes by operating the device at higher pressure.

However, all PEC devices reported thus far have been operating at atmospheric pressure (1 bar).

Enhancing the pressure

A team from the Institute for Solar Fuels at HZB has now investigated water splitting at elevated pressure under PEC-relevant conditions.

Side-view of O2 and H2 bubble curtains generated from Pt/FTO anode (A) and cathode (C), respectively. The experiment was performed in 1 M KOH electrolyte solution at 10 mA cm-2 and 4 bar. Credit Feng Liang /HZB

They used gas to pressurize PEC flow cells to between 1 and 10 bar and recorded a number of different parameters during electrolysis.

They also developed a multiphysics model of the PEC process and compared it with experimental data at normal and elevated pressure.

This model now allows us to play with the parameters and identify the key levers.

“For example, we investigated how the operating pressure affects the size of the gas bubbles and their behavior at the electrodes,” says Dr. Feng Liang, first author of the paper now published in Nature Communications.

Energy losses halved

The analysis shows that increasing the operating pressure to 8 bar halves the total energy loss, which could lead to a relative increase of 5-10 percent in overall efficiency.

“The optical scattering losses can be almost completely avoided at this pressure,” explains Liang.

“We also saw a significant reduction in product cross-over, especially the transfer of oxygen to the counter electrode.”

At higher pressures, however, there is no advantage, so the team suggests 6-8 bar as the optimum operating pressure range for PEC electrolyzer.

“These findings, and in particular the multiphysics model, can be extended to other systems and will help us to increase the efficiencies of both electrochemical and photocatalytic devices,” says Prof. Dr. Roel van de Krol, who heads the Institute for Solar Fuels at HZB.